Cavity Ringdown Spectroscopy of the Ã− X̃ Electronic Transition of the Phenyl Peroxy Radical
نویسندگان
چکیده
Cavity ringdown spectra (CRDS) of the near IR Ã2A′ X̃2A′′ electronic transition of phenyl peroxy radical are reported. The electronic origin is observed at 7497 cm−1. Ab initio calculations have been carried out to aid the assignement of the electronic origin and other bands involving vibrational excitation.
منابع مشابه
Observation of the à − X̃ Electronic Transition of the CF 3 O 2 Radical
The first observation of a sharp, structured electronic spectrum for a fluorinated alkyl peroxy radical is reported using the technique of cavity ringdown spectroscopy (CRDS). The T00 value for the Ã2A′ − X̃2A′′ transition of CF3O2 has been determined to be 6656(3) cm−1; values for à state vibrational frequencies have also been determined. Initial kinetic observations on CF3O2 have been carried ...
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